Zeolitemodified electrodes and electrodemodified zeolites. Three zeolites were used, linde type a za, faujasite zy, and mfi zsm5. The electrochemical behaviour of hydrogen peroxide at the surface of modified electrode was investigated by cyclic voltammetry and chronoamperometry in 0. Zeolitemodified solgel electrode as an electrochemical. The screenprinted zeolite modified electrode spzme resulted in faster accumulation and release of the electroactive probe compared to the zeolite modified carbon paste electrode zmcpe. Orozco, sl, bandala, er, arancibiabulnes, ca, serrano, b. A sensitive and selective voltammetric method using feiii encapsulated zeolite graphite composite modified glassy carbon electrode is presented in this work for the determination of paracetamol in tablet formulations. Simultaneousselective detection of dopamine and ascorbic. Voltammetric detection of urea on an agmodified zeolite. As the increased of hno 3 modified zeolite dosage ranged from 0. Modified electrode based on zeoliteencapsulated criii complex. Anew zeolite modified electrode was prepared by using zeolite polyvinyl as amodifier on gce. Again, as the medium of electrocatalysis using zeolite modified electrode zme is either acidic or alkaline so the impact of acid and alkali on zeolite porosity and acidity is vital. Electrocatalytic reduction of phch2cl on agzsm5 zeolite modified electrode guojiao sui, qilong sun, di wu, wangjun meng, huan wang, jiaxing lu shanghai key laboratory of green chemistry and chemical processes, school of chemistry and molecular engineering, east china normal university, shanghai 200062, china 1.
Natural zeolites in water treatment how effective is. Determination of mercuryii using a modified electrode. Agdoped zeolite modified expanded graphite composite electrode agzege was prepared and applied for the electrochemical determination of nitrate anion from aqueous solution. Iron iii exchanged in zeolite y act as catalyst to oxidize uric acid. Appearance of oxidative peak current with an over threefold enhancement at significantly reduced. Determination of copper by zeolite molecular sieve modified. They are based either on the physical anchoring of zeolite particles on the surface of solid carbon paste the viscosity of which can be tuned by temperature change or controlled dissolution by an organic solvent, or on the dispersion of zeolite particles in the bulk of a carbon paste matrix containing solid paraffin as a binder. Fuel cell applications of chemically synthesized zeolite. The zeolitemodified carbon paste electrode was immerse d in the cell containing the stirred copper solution and the effe ct of ac cumulation time w as studied. In order to use the modified zeolite as the electrode material, the zeolite sample was homogeneously dispersed in 5 wt. Carbon paste electrode modified imprinted zeolite as a. Evaporation of zeolite polymer suspensions zeolite polystyrene composite. The electrochemical characterization of nizmcpe exhibits redox behavior of niiiiniii couple in alkaline.
A simple and an effective catalyst for determination of. Determination of copper by zeolite molecular sieve. With this mixture as the electrode material, oxidation of hydroxide ions was studied by cyclic voltammetry. Pdf 4 implication of zeolite chemistry in electrochemical science. A cap member comprising yttriastabilized zirconia closes one end of the tube. Carbon materials in the forms of graphite, glassy carbon, carbon fibers, carbon nanotubes, etc. Chemically modified carbon paste electrodes are prepared by incorporating appropriate quantities of a zeolite directly into the paste mixture. Comparison of zeolitemodified electrodes with a graphite electrode. The carbon electrode with zeolite denoted as a zeolite modified carbon electrode zmce was prepared by the slurry and pasting method with zeolite particles and carbon black. Evaporation of zeolitepolymer suspensions zeolitepolystyrene composite. A potentiometric sensor for nitrogen oxide no x measurement based on yttriastabilized zirconia with a zeolite modified electrode is presented.
The zeolitemodified carbon paste electrode sciencedirect. Electrochemical characterization of iron iii doped zeolite. The agzege exhibited the electrocatalytic activity towards the cathodic. Table 1 main reported methods for use of zeolites in electrochemistry and design of zeolite modi. This paper describes a new kind of zeolite modified electrodes zmes based on the physical immobilization of zeolite particles onto the surface of paraffinimpregnated graphite electrodes piges. A simple and effective zeolite modified electrode zme was constructed from cuiiexchanged clinoptilolite nanoparticles cuiicnp. Oxidation of hydroxide ions at platinummodified zeolite. Trace levels of mercuryii can be preconcentrated on these electrodes.
Surface phenomena, kinetics and thermodynamics studies sanghratna waghmare, tanvir arfin, sadhana rayalu, dilip lataye, samujjwala dubey, sangeeta tiwari. Us6843900b2 potentiometric nox sensors based on yttria. The mixture of zeolite and graphite has been proposed in various forms since the 1980s 7, leading to a class of electrodes named zeolite modified electrodes zmes 8. The synthesis of criii complexes encapsulated in supercages of y zeolite was carried out by free diffusion of the pan 12pyridylazo2naphtol ligand figure 1 through the zeolite pores exchanged with the criii metal ion, obtained by.
Biosensors based on nanogoldzeolitemodified ion selective. This paper is solely concerned with the mechanism of electron transfer in zeolite modified electrodes zmes where the zeolite has been modified with electroactive transition metal ions or complexes. Zeolite coatings on conventional electrode substrates a1. Their electrochemical behavior was first evaluated by ionexchange voltammetry using methylviologen as a model redox probe, indicating better performance in comparison to the corresponding zeolite. Preconcentration and electroanalysis of copper at zeolite modified. International journal of analytical chemistry hindawi. Pdf voltammetric determination of paracetamol in tablet. With the purpose of obtaining inexpensive electrodes for the degradation of organic pesticides by the electrofenton reaction, the required h 2 o 2 being obtained by the 2electron reduction of dissolved o 2, we have prepared glassy carbon electrodes coated with a mixture of graphite with mo andor co modified zeolites.
Intra versus extrazeolite electron transfer chandana senaratne, j. The cap member has an interior surface exposed to the interior of. The concentration of cuii in waste water of gong fabrication, using carbon paste electrode modified with zeolite is 93. Electrodes based on zeolites modified with cobalt andor. A potentiometric sensor of the present invention comprises a tube having an interior and an exterior. Zeolite modified electrodes zmes have been drawing attention as chemically modified electrodes cmes because of synergistic combination of zeolite features with electrochemical interfaces 912. The synthesis of criii complexes encapsulated in supercages of y zeolite was carried out by free diffusion of the pan 12pyridylazo2naphtol ligand figure 1 through the zeolite pores exchanged with the criii metal ion, obtained by the previous use of the biosorption process 5.
Although paracetamol is known to have excellent safety profile at recommended therapeutic doses, health effects are also reported at acute overdoses. Lanthanum zeolite carbon paste electrode was synthesized and investigated as an alternative electrode for electrochemical detection of pbii and cdii ions. In the present study, an expanded graphiteag modified zeolite epoxy composite egagzepoxy electrode was prepared from romanian natural zeolitic volcanic tuff modified with silver, and electrochemically characterized for urea detection. Zmce exhibited a significantly enhanced efficiency in the removal of divalent ions in softening using the cdi process compared to the normal softening process based on.
Experiments on zeolite show that it is not electrochemically active. Voltammetric determination of paracetamol in tablet. The kjeldahl ammonia distillation technique and the ammonia electrode technique for measuring nh 3 give identical cec results. Zeolites have the capacity to be completely hydrated and dehydrated without damage to the crystalline lattice 1. Biosensors based on nanogold zeolite modified ion selective fieldeffect transistors for creatinine detection berna ozansoy kasap1, svitlana v. Zeolite modified electrodes and electrode modified zeolites rolison is known for her research on the modification of electrode surfaces with zeolites.
May 10, 2019 a conventional three electrode system was employed with a bare gce 3 mm in diameter, ch instruments, inc, or iron iii doped zeolite graphite composite modified glassy carbon electrode fzgcgce as working electrode, silversilver chloride agagcl as reference electrode and a platinum coil as a counter electrode. A zeolite modified carbon paste electrode based on copper exchanged clinoptilolite nanoparticles for voltammetric determination of metronidazole elahe shahnazarishahrezaie ab and alireza nezamzadehejhieh abc a department of chemistry, shahreza branch, islamic azad university, p. Pdf screenprinted zeolitemodified carbon electrodes. Gce were conducted by electrochemical impedance spectroscopy and cyclic voltammetry. Electrochemical behavior of carbon paste electrode modified with ni ii zeolite and its application for electrocatalytic oxidation of methanol. Gce was prepared by evaporation of solvent from dispersion of the zeolitegraphite mixture with the polymer in acetone. Effective electrofenton degradation of reactive black 5. Zeolitemodified electrodes with analytical applications. May 12, 2016 in the present work, nickel zeolite modified carbon paste electrode nizmcpe was prepared.
Adsorption behaviour of modified zeolite as novel adsorbents. Dzyadevych2,3 and burcu akata kurc1,4 abstract the combination of advantages of using zeolites and gold nanoparticles were aimed to be used for the. Zeolite modified solgel electrode as an electrochemical sensor for potentiometric determination of cesium ions in water samples. Carbon paste electrode modified imprinted zeolite have been developed as a sensor to analyze creatine by potentiometry. Characterization of immobilization of an enzyme in a modified y zeolite matrix and its application to an amperometric glucose biosensor. The catalytic electrochemical oxidation of urea on egagzepoxy electrode was investigated. Electrocatalytic characteristics of uric acid oxidation at. The zeolite modified electrodes were prepared as described elsewhere. Zeolitemodified electrodes gion calzaferri, research. Pdf on jul 31, 2003, alain walcarius and others published 4.
Zeolitemodified solid carbon paste electrodes springerlink. Electrochemical response as a probe of intracrystalline cationexchange dynamics in zeolites x and y chandana senaratne, and mark d. First, the electrochemical behavior of iron iii incorporated in the zeolite y modified electrode. Supporting information modified electrode electrocatalytic. Electrical contact was established via the contact between the paste, the copper tube and the disk arbor.
The journal of physical chemistry 1996, 100 14, 58495862. Iron iii doped zeolite graphite composite modified glassy carbon electrode was prepared for determination of uric acid in human urine samples. An efficient amperometric sensor for hydrogen peroxide by. The electrochemical behaviour of nitrate anions on the electrode was investigated by cyclic voltammetry in 0. In the electrochemical fields the zeolites have been used in electrocatalysis and.
Heavy metal ions removal from water using modified zeolite. Romanian agdoped zeolite is shown in the inset of figure 1 for comparison. Zeolitemodified paraffinimpregnated graphite electrode. A carbon paste electrode modified with zeolite was employed for quantities of copper. Electrochemical characterization of iron iii doped. Among the class of synthetic zeolites, zeolite a is considered one of the most important. Nov 02, 2017 in general, the rare earth metal impregnated zeolite modified electrode in any of its embodiments is contacted with an aqueous sample and in electrical communication with a reference electrode. Cobalt impregnated zeolitemodified electrode was prepared by mixing cobaltzeolite coz and graphite powder with different percentages. Determination of copper by zeolite molecular sieve modified electrode 597 procedure for the voltammetric experiment 40 ml of scanning solution were placed in the cell. Zeolite modified carbon paste electrode has good precision and accuration. In one electrode, graphite was replaced by linde molecular sieve zeolite 4a za and, in.
A potential is applied between the reference electrode and the rare earth metal impregnated zeolite modified electrode produce a current. It is found that acidtreatment doesnt affect significant structural and morphological changes apart from formation of hydroxyl. A conventional three electrode system was employed with a bare gce 3 mm in diameter, ch instruments, inc, or iron iii doped zeolite graphite composite modified glassy carbon electrode fzgcgce as working electrode, silversilver chloride agagcl as reference electrode and a platinum coil as a counter electrode. In the present work, nickel zeolite modified carbon paste electrode nizmcpe was prepared. Zeolite modified electrodes zmes have attracted considerable attention during the past years because they combine, in a single device, the specificity of charge transfer reactions with the intrinsic properties of the aluminosilicates, such as molecular sieving and ion exchange capacity. Gce was prepared by evaporation of solvent from dispersion of.
N2 the electrocatalytic production of hydroxyl radical ho on the surface of zeolite modified electrode me employing cu zeolites zsm5 and. Cyclic voltammetry is used to quantify the accumulated ions. Using the cyclic voltammetric technique, the electrochemical oxidation of hydrogen peroxide at such electrodes was investigated. New zeolite modified carbonbased electrodes are described.
The unmodified electrode carbon pastecpe was prepared with similar way without adding zeolite. The electrochemical behavior of paracetamol pct both at unmodified glassy carbon electrode and feiii doped zeolite graphite composite modified gc electrode fzggce has been investigated. Carbon paste electrode incorporating calciumexchanged zeolite modified with methylene blue for amperometric detection. Pdf preconcentration and electroanalysis of copper at. Electrochemical sensor based on low silica x zeolite modified. The electrochemical oxidation of cefixime at such electrodes was investigated using the cyclic voltammetric and amperometric techniques. Voltammetric measurements figure 2 depicts a detail of cvs of egagzepoxy composite electrode in 0. Electrochemical impedance spectroscopic and cyclic voltammetric results confirmed surface modification of the surface of glassy carbon electrodes. Two different zeolitemodified electrodes were employed in the study. Zme can be exploited as electrochemical sensors in relation with zeolite s properties, e. The relativestandard deviation of the response to 4. Pdf zeolitemodified electrodes with analytical applications. Imprinted zeolite iz was synthesized by mole ratio of creatinesi of 0.
In recent decades, zeolite modi ed electrodes zmes have been widely used in determination of di. Electrochemical determination of nitrate from water sample. Natural zeolites in water treatment how effective is their use 83 1. Researcharticle electrochemical characterization of iron iii doped zeolite graphite composite modified glassy carbon electrode and its application for adsasswv determination of. Zeolite used in this study was ts1 type zeolite that was synthesized with mole ratio of teos, tbot, tpaoh, and h 2 o of 1. Zeolite graphite composite modified glassy carbon electrode and its application for adsasswv determination of uric acid in human urine mearegamare. The electrode surface was polished on a lens paper. The purpose of this work is to evaluate the electroanalytical performance of ag doped zeolite modified expanded graphite composite electrode agzege for the determination of nitrate anion. Pdf zeolitemodified electrodes zmes have been widely investigated because of their chemical, physical, and structural characteristics shape, size. Gce was prepared by evaporation of solvent from dispersion of the zeolite graphite mixture with the polymer in acetone.
Synthesis and applications of molecular sieve layers and membranes. Pdf carbon paste electrode incorporating calciumexchanged. The response is characterized with respect to preconcentration, ph, and other variables. Preconcentration and electroanalysis of copper at zeolite modified carbon paste electrode. Zeolitemodified solid carbon paste electrodes request pdf. Table 1 main reported methods for use of zeolites in electrochemistry and design of zeolitemodi. Modified lanthanumzeolite for sensitive electrochemical.
Drinking and grey water treatment several conventional methods are used for the removal of pollutants from drinking water, such as coagulation followed by filtration, membrane processes and ion exchange. The modifier was characterized by ftir, bet, xrd and tem techniques. The electronic conductivity of the sample was enhanced by adding 10 wt. A zeolite modified carbon paste electrode based on copper.
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